An Equation for Anodic Stripping Curves of Thin Mercury-Film Electrodes.

Ultrasound-Enhanced Anodic Stripping Voltammetry Using Perfluorosulfonated Ionomer-Coated Mercury Thin-Film Electrodes

The high mass transport caused by ultrasonic radiation in the preconcentration of trace metal species in anodic stripping voltammetry (ASV), leads to an order of magnitude enhancement in sensitivity. A Nafion-coated mercury thin-film working electrode is placed in a specially designed small-volume sonovoltammetric cell. The preparation and curing procedure for the Nafion film on a glassy carbon...

Nafion-coated bismuth film and nafion-coated mercury film electrodes for anodic stripping voltammetry combined on-line with ICP-mass spectrometry.

Nafion-coated bismuth film electrodes (NCBFEs) and Nafion-coated mercury film electrodes (NCMFEs) were used to electrochemically preconcentrate metal analytes for subsequent analysis by inductively coupled plasma-mass spectrometry (ICP-MS). Either type of electrodes is part of a thin-layer electrochemical flow cell that is positioned upstream of a microconcentric nebulizer for the ICP-MS. Perfo...

Square Wave Anodic Stripping Voltammetry at the Mercury Film Electrode: Theoretical Treatment

The theoretical treatment of square wave anodic stripping voltammetry at a mercury film electrode Is presented. Numerlcal calculations, using the step method, show that the dlfferentlal current voltammograms are symmetrical and the peak potentlal, E,, shlfts to more negaflve potentials (anEd8 log A = 59.2 mV) with decreasing film thickness parameter A = / / ( D R ~ ) " * . For A < 0.3, peak cur...

LabVIEW-based sequential-injection analysis system for the determination of trace metals by square-wave anodic and adsorptive stripping voltammetry on mercury-film electrodes

The development of a dedicated automated sequential-injection analysis apparatus for anodic stripping voltammetry (ASV) and adsorptive stripping voltammetry (AdSV) is reported. The instrument comprised a peristaltic pump, a multiposition selector valve and a home-made potentiostat and used a mercury-film electrode as the working electrodes in a thin-layer electrochemical detector. Programming o...

Stripping voltammetric behavior of nitrogen-doped tetrahedral amorphous carbon thin film electrodes in NaCl solutions